Readily biodegradable and low-toxic biocompatible ionic liquids for cellulose processing

Marta Markiewicz , Joanna Maszkowska , Véronique Nardello-Rataj , Stefan Stolte

Abstract

Cellulose is an important feedstock for the chemical industry, but its processing is a challenge. Considerable efforts have been invested in applying the rules of green chemistry in developing environmentally more acceptable processes. Within this work we present an account on biocompatible, degradable ILs of low (eco)toxicity which could fi nd potential applications in the cellulose processing industry. We have tested ILs based on choline and betaine cations and the levulinate anion. We have discovered that, among these structures, betaine-ester levulinate is the most degradable and the least toxic IL. All tested structures were to some, sometimes high, extent degradable and showed low to moderate toxicity towards Daphnia magna , Vibrio fi scheri and rat leukaemia cells.
Author Marta Markiewicz
Marta Markiewicz,,
-
, Joanna Maszkowska PChZŚ
Joanna Maszkowska,,
- Laboratory of Chemical Environmental Risks
, Véronique Nardello-Rataj
Véronique Nardello-Rataj,,
-
, Stefan Stolte PChZŚ
Stefan Stolte,,
- Laboratory of Chemical Environmental Risks
Journal seriesRSC Advances, ISSN 2046-2069
Issue year2016
Vol6
No90
Pages87325-87331
Publication size in sheets0.5
DOIDOI:10.1039/c6ra14435g
URL http://pubs.rsc.org/en/content/articlepdf/2016/ra/c6ra14435g
Languageen angielski
LicenseJournal (articles only); published final; Uznanie Autorstwa - Użycie Niekomercyjne (CC-BY-NC); with publication
Score (nominal)35
ScoreMinisterial score = 30.0, 20-12-2017, ArticleFromJournal
Ministerial score (2013-2016) = 35.0, 20-12-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 3.108 (2) - 2016=3.257 (5)
Citation count*0
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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