Iminodiacetate complex of cobalt(II) - structure, physicochemical characteristics, biological properties and catalytic activity for 2-chloro-2-propen-1-ol oligomerization

Joanna Drzeżdżon , Jacek Malinowski , Artur Sikorski , Barbara Gawdzik , Przemysław Rybiński , Lech Chmurzyński , Dagmara Jacewicz

Abstract

A coordination complex, [Co(ida)(H2O)2] where ida denotes iminodiacetate, as a potential highly active catalyst was designed and obtained. To obtain a full structural characteristic, i.e. to determine the crystallographic details and the spatial structure of the crystals of the studied complex, X-ray analysis was carried out. [Co(ida)(H2O)2] was investigated also by elementary analysis, IR spectrophotometry and MALDI-TOF-MS to get a full physicochemical characteristics. The stoichiometry of [Co(ida)(H2O)2] in aqueous solutions was determined using the conductometric titrations. Consequently, the potentiometric titrations were performed to determine the thermodynamic stability of the title compound in aqueous solutions. Moreover, the antioxidant activity of [Co(ida)(H2O)2] against superoxide anion radical has been examined by NBT test. The catalytic properties of the cobalt(II) complex, [Co(ida)(H2O)2], were examined. It turned out that complex studied is a highly active catalyst for the 2-chloro-2-propen-1-ol oligomerization. It catalyzes the reaction of oligomerization in mild conditions: under normal pressure and at room temperature. The oligomerization reaction products were fully characterized by the following spectroscopic methods: IR, NMR, MALDI-TOF-MS. Furthermore, to investigate the thermal behavior of the obtained oligomer, the product of the oligomerization obtained using [Co(ida)(H2O)2] as the catalyst was studied with the use of thermal analysis methods, i.e. DSC and TG. The catalytic activity of the title complex has also been calculated.
Author Joanna Drzeżdżon (FCh / DGICh / LPCC)
Joanna Drzeżdżon,,
- Laboratory of Physicochemistry of Coordination Complexes
, Jacek Malinowski (FCh / DGICh / LPCC)
Jacek Malinowski,,
- Laboratory of Physicochemistry of Coordination Complexes
, Artur Sikorski (FCh / DPCh / PK)
Artur Sikorski,,
- Pracownia Krystalochemii
, Barbara Gawdzik
Barbara Gawdzik,,
-
, Przemysław Rybiński
Przemysław Rybiński,,
-
, Lech Chmurzyński (FCh / DGICh / LPCC)
Lech Chmurzyński,,
- Laboratory of Physicochemistry of Coordination Complexes
, Dagmara Jacewicz (FCh / DGICh / LPCC)
Dagmara Jacewicz,,
- Laboratory of Physicochemistry of Coordination Complexes
Journal seriesPolyhedron, ISSN 0277-5387, (N/A 100 pkt)
Issue year2020
Vol175
Pages1-10
Publication size in sheets0.5
Article number114168
Keywords in English2-chloro-2-propen-1-ol, catalysis, cobalt(II) ion, iminodiacetate anion, oligomers
ASJC Classification1604 Inorganic Chemistry; 1606 Physical and Theoretical Chemistry; 2505 Materials Chemistry
DOIDOI:10.1016/j.poly.2019.114168
URL https://doi.org/10.1016/j.poly.2019.114168
Languageen angielski
Score (nominal)100
Score sourcejournalList
ScoreMinisterial score = 100.0, 12-03-2020, ArticleFromJournal
Publication indicators WoS Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2017 = 0.654; WoS Impact Factor: 2018 = 2.284 (2) - 2018=1.89 (5)
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