Photocatalytic activity of solvothermal prepared BiOClBr with imidazolium ionic liquids as a halogen sources in cytostatic drugs removal

Patrycja Wilczewska , Aleksandra Bielicka-Giełdoń , Agnieszka Fiszka-Borzyszkowska , Jacek Ryl , Tomasz Klimczuk , Ewa Maria Siedlecka

Abstract

In this work, the BiOClBr, as a new family of bismuth based semiconductors, was successfully applied to remove of cytostatic drugs from water under UV-Vis light irradiation. BiOCl, BiOBr and BiOClBr were synthesized using two steps solvothermal method in glycerol. The inorganic salts (KCl and KBr) and 1-butyl-3-metylimidazolium chloride (BmimCl) and 1-butyl-3-metylimidazolium bromide (BmimBr) ionic liquids (ILs) were used as the source of halides for the photocatalysts synthesis. The as-fabricated samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and UV–vis diffuse reflectance spectroscopy (DRS). The specific surface area was measured by Brauner-Emmett-Teller (BET) technique. Additionally, Fourier-transform infrared spectroscopy was used to evaluate the presence of IL on the photocatalysts surface. The comparison of photocatalytic activity between BiOCl and BiOClBr photocatalysts towards 5-fluorouracil (5-FU), imatinib (IMA) and cyclophosphamide (CP) removal was conducted. The highest photocatalytic activity in the cytostatic drugs degradation and mineralization was found using BiOClBr IL synthetized via ILs as the halogens source. The study showed that BiOClBr IL synthesized in the presence of ILs can be a promising material in the water decontamination methods.
Author Patrycja Wilczewska (FCh / DET / LAOP)
Patrycja Wilczewska,,
- Laboratory of Advanced Oxidation Processes
, Aleksandra Bielicka-Giełdoń (FCh / DET / LAOP)
Aleksandra Bielicka-Giełdoń,,
- Laboratory of Advanced Oxidation Processes
, Agnieszka Fiszka-Borzyszkowska (FCh / DET / LAOP)
Agnieszka Fiszka-Borzyszkowska,,
- Laboratory of Advanced Oxidation Processes
, Jacek Ryl - [Politechnika Gdanska]
Jacek Ryl,,
-
- Politechnika Gdanska
, Tomasz Klimczuk - [Politechnika Gdanska]
Tomasz Klimczuk,,
-
- Politechnika Gdanska
, Ewa Maria Siedlecka (FCh / DET / LAOP)
Ewa Maria Siedlecka,,
- Laboratory of Advanced Oxidation Processes
Journal seriesJournal of Photochemistry and Photobiology A-Chemistry, ISSN 1010-6030, (N/A 70 pkt)
Issue year2019
Vol382
Pages1-11
Publication size in sheets0.5
Article number111932
Keywords in EnglishBiOClBr, photocatalysis, ionic liquids, synthesis, cytostatic drugs
ASJC Classification3100 General Physics and Astronomy; 1500 General Chemical Engineering; 1600 General Chemistry
DOIDOI:10.1016/j.jphotochem.2019.111932
URL https://doi.org/10.1016/j.jphotochem.2019.111932
Languageen angielski
Score (nominal)70
Score sourcejournalList
ScoreMinisterial score = 70.0, 29-11-2019, ArticleFromJournal
Publication indicators WoS Citations = 0; Scopus Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2018 = 0.851; WoS Impact Factor: 2018 = 3.261 (2) - 2018=2.915 (5)
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