Structural and luminescent study of TeO2-BaO-Bi2O3-Ag glass system doped with Eu3+ and Dy3+ for possible color-tunable phosphor application

Tomasz Lewandowski , Cezary Seweryński , Michalina Walas , Marcin Łapiński , Anna Synak , Wojciech Sadowski , Barbara Kościelska

Abstract

Tellurite glass systems of 73TeO(2)-4BaO-3Bi(2)O(3)-1Ag:xEu(2)O(3)-(2-x)Dy2O3 (where x = 0.5, 1, 1.5, 2 in molar ratio) composition have been successfully synthesized. In order to acquire Ag nanoparticles, materials have been heat treated at 350 degrees C in the air atmosphere. Structural properties of obtained samples were evaluated with various techniques. X-Ray Diffraction (XRD) measurements indicated that obtained materials are amorphous in nature. UV vis results presented transitions characteristic to Dy3+ and Eu3+ ions. Additionally, X-Ray Photoelectron Spectroscopy (XPS) analysis indicated the presence of silver in metallic form. Photoluminescence measurements shown influence of Ag nanoparticles on emission characteristics. Simultaneous emission of Dy3+ and Eu3+ has been observed when samples were excited with lambda(exc) = 390 nm. Change of the emission color induced by heat treatment has been observed and described in case of x =1 glass series. According to CIE results emission color changes as Eu/Dy ratio and heat treatment time are changed. Emission shifts from reddish-orange to yellowish white color. Obtained photoluminescence results confirm that synthesized materials are good candidates for color tunable phosphors.
Author Tomasz Lewandowski
Tomasz Lewandowski,,
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, Cezary Seweryński
Cezary Seweryński,,
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, Michalina Walas
Michalina Walas,,
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, Marcin Łapiński
Marcin Łapiński,,
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, Anna Synak (FMPI / IEP)
Anna Synak,,
- Institute of Experimental Physics
, Wojciech Sadowski
Wojciech Sadowski,,
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, Barbara Kościelska
Barbara Kościelska,,
-
Journal seriesOptical Materials, ISSN 0925-3467, e-ISSN 1873-1252, (A 30 pkt)
Issue year2018
Vol79
Pages390-396
Publication size in sheets0.5
Keywords in Englishsilver nanoparticles, luminescence, phosphor, tellurite glass
DOIDOI:10.1016/j.optmat.2018.03.031
URL https://doi.org/10.1016/j.optmat.2018.03.031
Languageen angielski
Score (nominal)35
ScoreMinisterial score = 30.0, 26-10-2018, ArticleFromJournal
Ministerial score (2013-2016) = 35.0, 26-10-2018, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 2.238 (2) - 2016=2.209 (5)
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