Oligomerization of 2-chloroallyl alcohol by 2-pyridinecarboxylate complex of chromium(III) - new highly active and selective catalyst

Joanna Drzeżdżon , Artur Sikorski , Lech Chmurzyński , Dagmara Jacewicz

Abstract

The new 2-pyridinecarboxylate (2-pic) complex of chromium(III) has been designed and synthesized as a new highly active and selective oligomerization catalyst. The crystal structure of the new compound has been determined by X-ray diffraction. The composition and purity of [Cr(2-pic)2(OH2)2]NO3 have been confirmed by several spectroscopic methods and the elemental analysis. Furthermore, the new complex has been investigated towards its catalytic activity for the oligomerization of 2-chloro-2-propen-1-ol under the atmospheric pressure and at room temperature. It has turned out that the novel catalyst exhibits a very high catalytic activity. Consequently, [Cr(2-pic)2(OH2)2]NO3 belongs to a new generation of non-metallocene catalysts.
Author Joanna Drzeżdżon PFZK
Joanna Drzeżdżon,,
- Laboratory of Physicochemistry of Coordination Complexes
, Artur Sikorski PK
Artur Sikorski,,
- Pracownia Krystalochemii
, Lech Chmurzyński PFZK
Lech Chmurzyński,,
- Laboratory of Physicochemistry of Coordination Complexes
, Dagmara Jacewicz PFZK
Dagmara Jacewicz,,
- Laboratory of Physicochemistry of Coordination Complexes
Journal seriesScientific Reports, ISSN 2045-2322
Issue year2018
Vol8
Pages1-7
Publication size in sheets0.5
DOIDOI:10.1038/s41598-018-26973-6
URL https://www.nature.com/articles/s41598-018-26973-6
Languageen angielski
LicenseJournal (articles only); published final; Uznanie Autorstwa (CC-BY); with publication
Score (nominal)40
ScoreMinisterial score = 40.0, 22-06-2018, ArticleFromJournal
Ministerial score (2013-2016) = 40.0, 22-06-2018, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 4.259 (2) - 2016=4.847 (5)
Citation count*0
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