Formation of 2-chloroallyl alcohol oligomers using a new crystalline dipicolinate complex of Cr(III) as a catalyst

Joanna Drzeżdżon , Dominika Zych , Jacek Malinowski , Artur Sikorski , Lech Chmurzyński , Dagmara Jacewicz

Abstract

A new chromium(III) complex with dipicolinate anion i.e. [Cr(dipic)(H2O)3]Cl ⋅ 2 H2O and its crystal structure, the physicochemical properties and catalytic activity for the oligomerization reaction of 2-chloro-2-propen-1-ol is presented in this report. The X-ray analysis of the new chromium(III) complex has been performed and based on the X-Ray analysis the crystallographic parameters have been determined. Conductivity titrations have been performed to determine the stoichiometry of the complex in aqueous solutions. The stability of the titled compound in aqueous solutions has been examined by potentiometric titrations. The nitro blue tetrazolium test has been carried out to check the antioxidant properties of [Cr(dipic)(H2O)3]Cl ⋅ 2 H2O. The oligomerization reaction of 2-chloro-2-propen-1-ol alcohol catalyzed by the titled chromium(III) complex has been conducted. The catalytic activity of [Cr(dipic)(H2O)3]Cl ⋅ 2 H2O has been calculated. The oligomerization products have been characterized using the nuclear magnetic resonance spectroscopy, the matrix-assisted laser desorption/ionization–time-of-flight mass spectrometry and the infrared spectroscopy.
Author Joanna Drzeżdżon (FCh / DGICh / LPCC)
Joanna Drzeżdżon,,
- Laboratory of Physicochemistry of Coordination Complexes
, Dominika Zych (FCh / DGICh / LPCC)
Dominika Zych,,
- Laboratory of Physicochemistry of Coordination Complexes
, Jacek Malinowski (FCh / DGICh / LPCC)
Jacek Malinowski,,
- Laboratory of Physicochemistry of Coordination Complexes
, Artur Sikorski (FCh / DPCh / PK)
Artur Sikorski,,
- Pracownia Krystalochemii
, Lech Chmurzyński (FCh / DGICh / LPCC)
Lech Chmurzyński,,
- Laboratory of Physicochemistry of Coordination Complexes
, Dagmara Jacewicz (FCh / DGICh / LPCC)
Dagmara Jacewicz,,
- Laboratory of Physicochemistry of Coordination Complexes
Journal seriesJournal of Catalysis, ISSN 0021-9517, (A 45 pkt)
Issue year2019
Vol375
Pages287-293
Publication size in sheets0.5
Keywords in Englisholigomerization, catalyst, chromium(III) complex, dipicolinate anion, crystal structure
ASJC Classification1606 Physical and Theoretical Chemistry; 1503 Catalysis
DOIDOI:10.1016/j.jcat.2019.06.011
URL https://doi.org/10.1016/j.jcat.2019.06.011
Languageen angielski
Score (nominal)45
ScoreMinisterial score = 40.0, 15-07-2019, ArticleFromJournal
Ministerial score (2013-2016) = 45.0, 15-07-2019, ArticleFromJournal
Publication indicators Scopus SNIP (Source Normalised Impact per Paper): 2017 = 1.85; WoS Impact Factor: 2017 = 6.759 (2) - 2017=7.502 (5)
Citation count*
Cite
Share Share

Get link to the record


* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
Back