Geometric isomerism effect on catalytic activities of bis(oxalato)diaquochromates(III) for 2-chloroallyl alcohol oligomerization

Joanna Drzeżdżon , Lech Chmurzyński , Dagmara Jacewicz


The cis- and trans-potassium bis(oxalato)diaquochromates(III) have been studied towards their catalytic activity for the 2-chloroallyl alcohol oligomerization. The geometric isomerism effect on the oligomerization products under mild reaction conditions has been investigated. The molecular masses and tactic structures of obtained poly(2-chloroallyl alcohols) have been compared and analyzed. The mechanisms of oligomerization processes have been proposed. It has been proven that two studied complexes – cis-K[Cr(C2O4)2(OH2)2] and trans-K[Cr(C2O4)2(OH2)2]·3H2O are highly active catalysts for the oligomerization of the beta-olefin derivative.
Author Joanna Drzeżdżon (FCh / DGICh / LPCC)
Joanna Drzeżdżon,,
- Laboratory of Physicochemistry of Coordination Complexes
, Lech Chmurzyński (FCh / DGICh / LPCC)
Lech Chmurzyński,,
- Laboratory of Physicochemistry of Coordination Complexes
, Dagmara Jacewicz (FCh / DGICh / LPCC)
Dagmara Jacewicz,,
- Laboratory of Physicochemistry of Coordination Complexes
Journal seriesJournal of Chemical Sciences, ISSN 0974-3626, (A 20 pkt)
Issue year2018
Publication size in sheets0.5
Keywords in Englishchromium(III) complexes, catalytic activities, polymerization, oxalate ion
Languageen angielski
Score (nominal)25
ScoreMinisterial score = 20.0, ArticleFromJournal
Ministerial score (2013-2016) = 25.0, ArticleFromJournal
Publication indicators WoS Impact Factor: 2017 = 1.254 (2) - 2017=1.291 (5)
Citation count*
Share Share

Get link to the record

* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.