Zastosowanie polikarboksylanowych związków kompleksowych w tworzeniu sieci metaloorganicznych typu MOF

Dominika Zych , Joanna Drzeżdżon , Lech Chmurzyński , Dagmara Jacewicz

Abstract

The first research on Coordination Polymers began at the beginning of the 20th century. Wider understanding of their structure has enabled the development of crystallography. Since then compounds, which belong to this group, have been the subject of broad-spectrum scientific research. A particular class of these compounds, known relatively recently, are Metal–Organic Frameworks (MOF). The MOF structure is based on negatively charged organic linkers, e.g. polycarboxylic anions connected to various metal cations or metal clusters. MOFs are mainly built up from metal cations: transition, alkaline earth, main groups of the periodic table, as well as rare earth metals. Moreover, organic ligands used in the construction of MOF materials should contain electron donors. A characteristic bond, that allows the formation of hybrids, through the interactions of nodes and bridges is the coordination bond. It allows to synthesize a three-dimensional framework structure. Modern synthesis leads to the generation of porous materials with a very large surface area of pores and unique properties. Considering their synthesis, crystalline structures and physicochemical properties of MOF, as well as broad MOFs applications including gas storage, separation, catalysts, luminescence, magnetism and others, it is reasonable to state that MOFs can be used in many areas, not only in science, but also in environmental protection and in industry, for example, energy industry, chemical and biochemical industry.
Author Dominika Zych (FCh / DGICh / LPCC)
Dominika Zych,,
- Laboratory of Physicochemistry of Coordination Complexes
, Joanna Drzeżdżon (FCh / DGICh / LPCC)
Joanna Drzeżdżon,,
- Laboratory of Physicochemistry of Coordination Complexes
, Lech Chmurzyński (FCh / DGICh / LPCC)
Lech Chmurzyński,,
- Laboratory of Physicochemistry of Coordination Complexes
, Dagmara Jacewicz (FCh / DGICh / LPCC)
Dagmara Jacewicz,,
- Laboratory of Physicochemistry of Coordination Complexes
Other language title versionsApplication of polycarboxylate comlexes in the formation of metal-organic frameworks
Journal seriesWiadomości Chemiczne, ISSN 0043-5104, e-ISSN 2300-0295, (N/A 0 pkt)
Issue year2019
Vol73
No5-6
Pages401-423
Publication size in sheets1.1
Keywords in Polishzwiązki metaloorganiczne typu MOF, trójwymiarowa struktura, fizykochemiczne właściwości związków typu MOF, zastosowanie związków typu MOF
Keywords in EnglishMetal-Organic Frameworks (MOF), three-dimensional framework structure, physicochemical properties of MOF, applications MOFs
URL https://ptchem.pl/storage/pages/June2019/5_6_2019.pdf
Languagepl polski
Score (nominal)5
ScoreMinisterial score = 5.0, 30-09-2019, ArticleFromJournal
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