Aquation reaction of iminodiacetate complex of oxidovanadium(IV) with 2,2’-bipyridine induced by Fe(III) ions: kinetic studies

Joanna Drzeżdżon , Agnieszka Piotrowska-Kirschling , Lech Chmurzyński , Dagmara Jacewicz

Abstract

The kinetics of the aquation reaction of the [VO(ida)(bipy)]·2H2O (VO(ida)(bipy)) complex (where ida = iminodiacetate anion and bipy = 2,2’-bipyridine) promoted by [Fe(H2O)6]3+ ions were investigated in aqueous solutions. Spectrophotometric studies were carried out at different temperatures in the range of 293.15–313.15 K. The concentration of the [Fe(H2O)6]3+ (Fe3+) ions was kept within the range of 2 × 10–4 to 8 × 10–4 mol L–1, and the concentration of VO(ida)(bipy) was 1 × 10–3 mol L–1. The values of the observable reaction rate constants were calculated based on the Glint computer program. Furthermore, the mechanism for the aquation of VO(ida)(bipy), induced by Fe(III) ions, has been proposed.
Author Joanna Drzeżdżon (FCh / DGICh / LPCC)
Joanna Drzeżdżon,,
- Laboratory of Physicochemistry of Coordination Complexes
, Agnieszka Piotrowska-Kirschling (FCh / DGICh / LPCC)
Agnieszka Piotrowska-Kirschling,,
- Laboratory of Physicochemistry of Coordination Complexes
, Lech Chmurzyński (FCh / DGICh / LPCC)
Lech Chmurzyński,,
- Laboratory of Physicochemistry of Coordination Complexes
, Dagmara Jacewicz (FCh / DGICh / LPCC)
Dagmara Jacewicz,,
- Laboratory of Physicochemistry of Coordination Complexes
Journal seriesProgress in Reaction Kinetics and Mechanism, ISSN 1468-6783, (N/A 20 pkt)
Issue year2019
Vol44
No4
Pages300-306
Keywords in Englishkinetics, aquation, oxidovanadium(IV) complexes, iminodiacetate, 2,2’-bipyridine
ASJC Classification1606 Physical and Theoretical Chemistry
DOIDOI:10.1177/1468678319850496
Languageen angielski
Score (nominal)20
Score sourcejournalList
ScoreMinisterial score = 20.0, 06-12-2019, ArticleFromJournal
Publication indicators WoS Citations = 0; Scopus Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 0.3; WoS Impact Factor: 2018 = 0.582 (2) - 2018=0.589 (5)
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